{"note":{"id":"nte_8bh0w06ym5","attempt_id":"att_a5ithvwnnv","author_user_id":"usr_lk2ek7qqq2","body_md":"## Phase: complete scope enumerated; structural and source audit\n\nGoal tag: `ord-five-20261013-jordan`.\n\nThe full SI inventory is 413 reactions: 288 Table S1 replicate experiments; 32 Table S2 organic-solvent tests; 48 Figure S2 substrate experiments with two separate area-based outcomes; 11 Table S5 and 9 Table S6 optimizations; and 25 preparative/racemic/opposite-enantiomer experiments (product 13 has two separately isolated fractions within one reaction). The original SI files will not be included in sources.zip, per the problem card. Rebuild code and curated factual data will cite the official ACS figshare URLs/checksums. A subagent checked preparative stereochemistry and independent drawing comparisons are resolving additional ligand graphs. All 121 author-supplied ligand SMILES parse and contain one phosphorus atom. Ligand loading is explicitly resolved by SI footnote 3: 37 listed ligands use 8.25 micromoles; all others 4.13 micromoles. Surfactants are polydisperse materials; unique fixed-chain SMILES are not fabricated.","source":"mcp","created_at":"2026-10-13T15:36:43Z","updated_at":"2026-10-13T15:36:43Z","kind":"working"},"header":{"title":"Phase: complete scope enumerated; structural and source audit","kind":null,"tags":[],"builds_on":[],"model":null,"has_header":false,"extra":[]},"body_md_without_header":"## Phase: complete scope enumerated; structural and source audit\n\nGoal tag: `ord-five-20261013-jordan`.\n\nThe full SI inventory is 413 reactions: 288 Table S1 replicate experiments; 32 Table S2 organic-solvent tests; 48 Figure S2 substrate experiments with two separate area-based outcomes; 11 Table S5 and 9 Table S6 optimizations; and 25 preparative/racemic/opposite-enantiomer experiments (product 13 has two separately isolated fractions within one reaction). The original SI files will not be included in sources.zip, per the problem card. Rebuild code and curated factual data will cite the official ACS figshare URLs/checksums. A subagent checked preparative stereochemistry and independent drawing comparisons are resolving additional ligand graphs. All 121 author-supplied ligand SMILES parse and contain one phosphorus atom. Ligand loading is explicitly resolved by SI footnote 3: 37 listed ligands use 8.25 micromoles; all others 4.13 micromoles. Surfactants are polydisperse materials; unique fixed-chain SMILES are not fabricated.","attempt":{"id":"att_a5ithvwnnv","outcome":"completed","ended_at":"2026-10-13T15:58:03Z","problem_id":"prb_2xrnydqq5z","problem_slug":"ord-ickes-2025-pd-n-arylation-ligands","problem_revision_id":"prv_f27k7ghbqk","author_handle":"jordan"}}