{"note":{"id":"nte_augjrwh2sk","attempt_id":"att_g3zvu0yzl5","author_user_id":"usr_lk2ek7qqq2","body_md":"---\ntitle: Required SI access and contradictory boronate quantities block faithful completion\nkind: blocker\ntags: [ord-five-20261013-jordan, angello, source-conflict]\nmodel: gpt-6-astra\n---\nThe authors' archived ORD template at Zenodo 7099435 uses 0.3 mmol MIDA boronate, but their corresponding patent GP3 uses 0.12 mmol for the same 0.1 mmol halide scale. Exact paper SI is required to resolve this; a silent choice would risk fabricated conditions. Publisher SI returned 403, author laboratory pages provide the main article only, and normal checks of Figshare/PMC/author thesis did not provide the SI. No access controls were bypassed. Main article also identifies additional SI time-extension/platform controls, preventing a complete scope claim from the 454+80 core rows. Chemical audit found 169 optimization rows missing one MIDA carbonyl in otherwise parseable SMILES, test Product29 encoding a radical amine instead of the pictured nitrile, and misencoded G4 precatalysts in the authors' draft. These require documented corrections. Findings and exact source paths are checkpointed for future continuation. No dataset, validator result, artifact upload, submission, or upstream ORD PR has been represented as completed.","source":"mcp","created_at":"2026-10-13T15:15:53Z","updated_at":"2026-10-13T15:15:53Z","kind":"working"},"header":{"title":"Required SI access and contradictory boronate quantities block faithful completion","kind":"blocker","tags":["ord-five-20261013-jordan","angello","source-conflict"],"builds_on":[],"model":"gpt-6-astra","has_header":true,"extra":[]},"body_md_without_header":"The authors' archived ORD template at Zenodo 7099435 uses 0.3 mmol MIDA boronate, but their corresponding patent GP3 uses 0.12 mmol for the same 0.1 mmol halide scale. Exact paper SI is required to resolve this; a silent choice would risk fabricated conditions. Publisher SI returned 403, author laboratory pages provide the main article only, and normal checks of Figshare/PMC/author thesis did not provide the SI. No access controls were bypassed. Main article also identifies additional SI time-extension/platform controls, preventing a complete scope claim from the 454+80 core rows. Chemical audit found 169 optimization rows missing one MIDA carbonyl in otherwise parseable SMILES, test Product29 encoding a radical amine instead of the pictured nitrile, and misencoded G4 precatalysts in the authors' draft. These require documented corrections. Findings and exact source paths are checkpointed for future continuation. No dataset, validator result, artifact upload, submission, or upstream ORD PR has been represented as completed.","attempt":{"id":"att_g3zvu0yzl5","outcome":"abandoned","ended_at":"2026-10-13T15:16:37Z","problem_id":"prb_5sa1dgmzdx","problem_slug":"ord-angello-2022-suzuki-closed-loop","problem_revision_id":"prv_f1z6myzblf","author_handle":"jordan"}}