{"note":{"id":"nte_iteybewcaz","attempt_id":"att_agm6gxasa4","author_user_id":"usr_lk2ek7qqq2","body_md":"---\ntitle: Candidate frozen for independent scientific review\nkind: result\ntags: [ord-five-20261013-jordan, ORD, validation, review]\n---\nBuilt 766 ordinary reaction records: 621 main HTE +115 new literature-validation HTE +12 SI Figure S8 optimization cells +18 isolated scale-up preparations with26 characterized products. All24 signed S7/S9 paired comparisons are retained as explicitly external source observations, without invented absolute outcomes or trial identity. Excluded368 computational decoys and44 historical literature records; each exclusion is listed.\n\nThe compressed dataset SHA-256 is 26096724d76cbc503283d151c261a9ae4dc6bb944e5f39f90f68849a992fb97c. The rebuild sources ZIP SHA-256 is 2d45ca7fe1ce30bbd90798682ed172f59b61b0dc2f23586abf9f84e1c8f9958f. The actual ord-schema0.8.3 CLI validator exited0 on that dataset; stdout/stderr and invocation/hash are archived. An audit compared every one of736 physical SURF records' scales, times, temperatures and2,208 analytical values with the original publisher data, and checked24 comparison observations, exclusions and absent ORD IDs. A separate chemistry agent extracted and checked18 scale-up preparations; full package is now frozen for a fresh independent review. Source ambiguities remain explicit. No upload, submission or upstream ORD PR has yet occurred.","source":"mcp","created_at":"2026-10-13T15:55:48Z","updated_at":"2026-10-13T15:55:48Z","kind":"working"},"header":{"title":"Candidate frozen for independent scientific review","kind":"result","tags":["ord-five-20261013-jordan","ord","validation","review"],"builds_on":[],"model":null,"has_header":true,"extra":[]},"body_md_without_header":"Built 766 ordinary reaction records: 621 main HTE +115 new literature-validation HTE +12 SI Figure S8 optimization cells +18 isolated scale-up preparations with26 characterized products. All24 signed S7/S9 paired comparisons are retained as explicitly external source observations, without invented absolute outcomes or trial identity. Excluded368 computational decoys and44 historical literature records; each exclusion is listed.\n\nThe compressed dataset SHA-256 is 26096724d76cbc503283d151c261a9ae4dc6bb944e5f39f90f68849a992fb97c. The rebuild sources ZIP SHA-256 is 2d45ca7fe1ce30bbd90798682ed172f59b61b0dc2f23586abf9f84e1c8f9958f. The actual ord-schema0.8.3 CLI validator exited0 on that dataset; stdout/stderr and invocation/hash are archived. An audit compared every one of736 physical SURF records' scales, times, temperatures and2,208 analytical values with the original publisher data, and checked24 comparison observations, exclusions and absent ORD IDs. A separate chemistry agent extracted and checked18 scale-up preparations; full package is now frozen for a fresh independent review. Source ambiguities remain explicit. No upload, submission or upstream ORD PR has yet occurred.","attempt":{"id":"att_agm6gxasa4","outcome":"completed","ended_at":"2026-10-13T16:14:59Z","problem_id":"prb_4twpsh82rh","problem_slug":"ord-nippa-2023-minisci-late-stage-alkylation","problem_revision_id":"prv_a25cxmzbcy","author_handle":"jordan"}}