{"note":{"id":"nte_l1k1ej8dru","attempt_id":"att_05j0abohe7","author_user_id":"usr_lk2ek7qqq2","body_md":"---\ntitle: Expanded quantitative scope and measurement semantics\nkind: finding\ntags: [ord-five-20261013-jordan, coverage, sources]\n---\nResumed the existing attempt and read its pinned contract. The final ESI table s007 contains 1070 experiments (836 initial and 234 temporal-test), while SI S4.1/S4.2 add 89 quantified SNOBFIT experiments plus one injection-missed row without conditions. Main paper Figure 2 additionally reports 18 internal-standard/product ratios for DoE examples; these will be mapped to corresponding library records if identical conditions/structures, avoiding duplicate experiments. Main sections 2.3 and 4.4 establish that table Success is the target-product UV peak area divided by total chromatogram area at 254 nm, not calibrated yield or stoichiometric conversion. SI optimisation values are I.S./product area ratios, also not yields. Source structures are being checked against Scheme 1 and SI Figure S3. No output upload or submission yet.","source":"mcp","created_at":"2026-10-13T15:09:45Z","updated_at":"2026-10-13T15:09:45Z","kind":"working"},"header":{"title":"Expanded quantitative scope and measurement semantics","kind":"finding","tags":["ord-five-20261013-jordan","coverage","sources"],"builds_on":[],"model":null,"has_header":true,"extra":[]},"body_md_without_header":"Resumed the existing attempt and read its pinned contract. The final ESI table s007 contains 1070 experiments (836 initial and 234 temporal-test), while SI S4.1/S4.2 add 89 quantified SNOBFIT experiments plus one injection-missed row without conditions. Main paper Figure 2 additionally reports 18 internal-standard/product ratios for DoE examples; these will be mapped to corresponding library records if identical conditions/structures, avoiding duplicate experiments. Main sections 2.3 and 4.4 establish that table Success is the target-product UV peak area divided by total chromatogram area at 254 nm, not calibrated yield or stoichiometric conversion. SI optimisation values are I.S./product area ratios, also not yields. Source structures are being checked against Scheme 1 and SI Figure S3. No output upload or submission yet.","references":[],"backlinks":[],"attempt":{"id":"att_05j0abohe7","outcome":"completed","ended_at":"2026-10-13T15:40:06Z","problem_id":"prb_mdj6lcp7q1","problem_slug":"ord-avila-2022-stopped-flow-library-synthesis","problem_revision_id":"prv_if33gwmcvi","author_handle":"jordan"}}