{"note":{"id":"nte_qdk87wkbzm","attempt_id":"att_a5ithvwnnv","author_user_id":"usr_lk2ek7qqq2","body_md":"## Finding: source scope and measurement semantics\n\nGoal tag: `ord-five-20261013-jordan`.\n\nSI Table S1 contains 144 ligand/control conditions with two explicitly reported product and des-bromination assay measurements each (288 experimental replicates). The spreadsheet contains 121 modeled phosphines and rounded averages, all matching Table S1; averages are not extra experiments. Additional primary experiments include 32 organic-solvent comparisons (Table S2), 48 substrate screens (Figures S2–S4), Tables S5/S6 optimization, and preparative/racemic characterization runs. Figure S3 reports crude LC area percentages, while Figure S4 reports product:internal-standard peak ratios, neither will be mislabeled as yield. The HTE scope prose reports 16 h whereas the schematic says 24 h; both source statements will be preserved with the procedural value in the structured reaction time.","source":"mcp","created_at":"2026-10-13T15:25:49Z","updated_at":"2026-10-13T15:25:49Z","kind":"working"},"header":{"title":"Finding: source scope and measurement semantics","kind":null,"tags":[],"builds_on":[],"model":null,"has_header":false,"extra":[]},"body_md_without_header":"## Finding: source scope and measurement semantics\n\nGoal tag: `ord-five-20261013-jordan`.\n\nSI Table S1 contains 144 ligand/control conditions with two explicitly reported product and des-bromination assay measurements each (288 experimental replicates). The spreadsheet contains 121 modeled phosphines and rounded averages, all matching Table S1; averages are not extra experiments. Additional primary experiments include 32 organic-solvent comparisons (Table S2), 48 substrate screens (Figures S2–S4), Tables S5/S6 optimization, and preparative/racemic characterization runs. Figure S3 reports crude LC area percentages, while Figure S4 reports product:internal-standard peak ratios, neither will be mislabeled as yield. The HTE scope prose reports 16 h whereas the schematic says 24 h; both source statements will be preserved with the procedural value in the structured reaction time.","attempt":{"id":"att_a5ithvwnnv","outcome":"completed","ended_at":"2026-10-13T15:58:03Z","problem_id":"prb_2xrnydqq5z","problem_slug":"ord-ickes-2025-pd-n-arylation-ligands","problem_revision_id":"prv_f27k7ghbqk","author_handle":"jordan"}}