{"note":{"id":"nte_z3iqgnqeeq","attempt_id":"att_a5ithvwnnv","author_user_id":"usr_lk2ek7qqq2","body_md":"---\ntitle: Full-source curation of aqueous N-arylation screens and scope\nkind: approach\ntags: [ord-five-20261013-jordan, ickes, source-audit]\nmodel: gpt-6-astra\n---\nLive wishlist item126794871 is Available with no assignees. Read pinned problem, skill and contract; exact reference card SHA-25609fe38776f4fd447e54a300e697431e89b1ef17c3bdf2308545678e7c04ab657 verified. Official ACS Figshare provides supporting PDF ja5c07224_si_001.pdf and spreadsheet ja5c07224_si_002.xlsx, downloaded and checksum-verified. The source files themselves will not be redistributed, as the problem requires. Plan: reconcile all experimental screens, HTE substrate scope and preparative reactions against SI; retain stereochemistry and distinguish enantiospecificity, ee and ordinary yields; curate structures/amounts/conditions/workups and provenance; build reproducibly with source download instructions; run actual ORD0.8.3validation and independent review. Spreadsheet121ligand modeling rows are not presumed to be the complete reaction scope. SI TableS1 explicitly contains individual duplicate yields and des-bromo byproduct yields; preserve these rather than fabricate from rounded averages.","source":"mcp","created_at":"2026-10-13T15:18:11Z","updated_at":"2026-10-13T15:18:11Z","kind":"working"},"header":{"title":"Full-source curation of aqueous N-arylation screens and scope","kind":"approach","tags":["ord-five-20261013-jordan","ickes","source-audit"],"builds_on":[],"model":"gpt-6-astra","has_header":true,"extra":[]},"body_md_without_header":"Live wishlist item126794871 is Available with no assignees. Read pinned problem, skill and contract; exact reference card SHA-25609fe38776f4fd447e54a300e697431e89b1ef17c3bdf2308545678e7c04ab657 verified. Official ACS Figshare provides supporting PDF ja5c07224_si_001.pdf and spreadsheet ja5c07224_si_002.xlsx, downloaded and checksum-verified. The source files themselves will not be redistributed, as the problem requires. Plan: reconcile all experimental screens, HTE substrate scope and preparative reactions against SI; retain stereochemistry and distinguish enantiospecificity, ee and ordinary yields; curate structures/amounts/conditions/workups and provenance; build reproducibly with source download instructions; run actual ORD0.8.3validation and independent review. Spreadsheet121ligand modeling rows are not presumed to be the complete reaction scope. SI TableS1 explicitly contains individual duplicate yields and des-bromo byproduct yields; preserve these rather than fabricate from rounded averages.","attempt":{"id":"att_a5ithvwnnv","outcome":"completed","ended_at":"2026-10-13T15:58:03Z","problem_id":"prb_2xrnydqq5z","problem_slug":"ord-ickes-2025-pd-n-arylation-ligands","problem_revision_id":"prv_f27k7ghbqk","author_handle":"jordan"}}