{
  "source": "ORD Dataset Wishlist",
  "snapshot_date": "2026-09-25",
  "ord_wishlist_status_at_snapshot": "Available",
  "ord_wishlist_card": "https://github.com/orgs/open-reaction-database/projects/11?pane=issue&itemId=126569980",
  "ord_data_issue": null,
  "title": "Towards Economical Lignin Utilization Through Reductive Catalytic Fractionation",
  "doi": null,
  "journal": "thesis",
  "publication_date": "2023-12-26",
  "authors": [],
  "article_open_access": null,
  "dataset_size_estimate": 600,
  "experiment_type": "HTE, biomass",
  "ord_priority": null,
  "ord_difficulty": null,
  "source_data_kind": "author_request_needed",
  "smiles_in_source": "partial",
  "needs_author_contact": true,
  "data_locations": [
    {
      "url": "https://www.proquest.com/openview/18cb8dff68ec54385bc9916cef333f28/1",
      "what": "PhD thesis (Towards Economical Lignin Utilization Through Reductive Catalytic Fractionation, 2023); abstract page only, full text not checked",
      "license": "unknown (thesis; ProQuest)"
    },
    {
      "url": "https://europepmc.org/article/PMC/PMC11200236",
      "what": "Related paper: Design and Validation of a High-Throughput Reductive Catalytic Fractionation Method, JACS Au 2024 (doi 10.1021/jacsau.4c00126). SI = au4c00126_si_001.pdf (methods, GC-FID/NMR analysis, supplementary figures and tables) and au4c00126_si_002.zip (plate design drawings per the SI description); includes a screen of 50 switchgrass samples",
      "license": "CC-BY-4.0 (article, per Crossref)"
    },
    {
      "url": "https://doi.org/10.17504/protocols.io.bp2l6x6jdlqe/v1",
      "what": "protocols.io analytical method for RCF aromatic monomers by LC-DAD (method only, not reaction data); seen in Crossref search results only",
      "license": "CC-BY-4.0 (per Crossref)"
    }
  ],
  "notes": "The source is a 2023 PhD thesis on reductive catalytic fractionation (RCF) of lignocellulosic biomass that includes roughly 600 high-throughput RCF runs; it has no DOI, and only the ProQuest abstract is public. For this DOI-less thesis, cite the exact thesis URL bound in card.allowed_publication_urls using provenance.publication_url; do not invent a DOI or cite a related paper as if it reported every thesis experiment. ORD 0.8.3 supports publication_url without a DOI; ORD maintainers separately judge source eligibility. A related open-access paper is 'Design and Validation of a High-Throughput Reductive Catalytic Fractionation Method', JACS Au 2024, doi 10.1021/jacsau.4c00126 (CC-BY 4.0; also PMC11200236). Its SI consists of a PDF (methods, GC-FID and 1H NMR analysis, supplementary figures and tables) and a ZIP of plate reactor design drawings. No machine-readable per-run data file was found. Whether the paper or thesis contains all ~600 runs is unverified; the full run table likely needs the authors. Inputs are biomass feedstocks (e.g., poplar, switchgrass) and heterogeneous metal catalysts. Outputs are aromatic lignin monomers (e.g., 4-propylguaiacol, 4-propylsyringol), yields as wt% of lignin.",
  "verification_caveats": "Biomass substrates have no SMILES and must be encoded as named/characterised materials (composition, lignin content). Catalysts are heterogeneous supported metals. Products are a monomer distribution reported as wt% yields relative to lignin, not molar yields of a single product. Source-document ambiguity: the thesis and the paper may cover different or overlapping run sets.",
  "allowed_publication_urls": [
    "https://www.proquest.com/openview/18cb8dff68ec54385bc9916cef333f28/1"
  ]
}