{"revision":{"id":"prv_b0m13ho1ix","problem_id":"prb_zquiq0r1iy","revision_number":1,"statement_md":"# Curate this paper into an ORD dataset\n\nBuild an Open Reaction Database (ORD) dataset of the reactions reported in:\n\n- **Paper:** Substrate-Photocatalyst Reactivity Matching Enables Broad Aryl Halide Scope in Light-Driven, Reductive Cross-Electrophile Coupling Using 13C NMR as a Predictor\n- **Authors:** Cameron H. Chrisman, W. Zachary Elder, Graham C. Haug et al.\n- **Published:** ACS Catalysis, 2025-05-01\n- **DOI:** [10.1021/acscatal.5c02019](https://doi.org/10.1021/acscatal.5c02019)\n- **ORD wishlist card:** [open on GitHub](https://github.com/orgs/open-reaction-database/projects/11?pane=issue&itemId=126980452)\n\nThe reference input `card` holds these facts, the source-data locations and the notes below in machine-readable form.\n\n## Scope\n\nEvery reaction the paper reports with its data (the wishlist estimates about 500 reactions; HTE): inputs with amounts and roles, conditions, workups, outcomes and provenance, following the `ord-curation` Skill. Submit one ORD Dataset for the paper; if its data come from several screens or methods, keep them together and say so in the dataset description.\n\n## Source data\n\nPaper: https://doi.org/10.1021/acscatal.5c02019 (ACS Catalysis 2025), an HTE study of light-driven reductive cross-electrophile coupling of aryl halides, pairing substrates with photocatalysts. According to the ORD curator notes, the Supporting Information PDF contains the data as plate maps plus tables, about 500 reactions. The compounds are given as structure drawings, so every substrate, photocatalyst and product must be converted to SMILES. The article is not open access; get the SI from the publisher page. Check whether the plate-map values are real text or embedded images before committing to the work.\n\nKnown locations:\n\n- [https://doi.org/10.1021/acscatal.5c02019](https://doi.org/10.1021/acscatal.5c02019): Article (ACS Catalysis 2025). Crossref lists only ACS policy licenses, and OpenAlex marks it closed. (license: closed (ACS standard terms))\n- [https://pubs.acs.org/doi/suppl/10.1021/acscatal.5c02019](https://pubs.acs.org/doi/suppl/10.1021/acscatal.5c02019): SI PDF with plate maps and tables (per ORD curator notes) (license: unknown (ACS SI))\n\n## Pitfalls\n\nPlate maps may be color-coded images with embedded values. Structure-to-SMILES conversion by hand or OCSR is error-prone. There are probably several screens: a substrate-photocatalyst matrix and a scope. Yield type (assay or isolated) is unknown.\n\n## Deliver\n\n- `dataset`: the ORD Dataset, compressed (`.binpb.gz`, `.pb.gz`, `.txtpb.gz`, `.pbtxt.gz` or `.parquet`), citing the DOI above in every reaction's provenance, with no dataset or reaction IDs.\n- `sources`: a `.zip` with a `README.md` (which tables or files each part came from, how structures were checked), the template and spreadsheet or the script or notebook that rebuild the dataset, and `validation.txt`, the output of ORD's validator (ord-schema 0.8.3) on the `dataset` file.\n\n## Before you start\n\nOpen the wishlist card. If it is no longer Available, someone has reserved or started it: coordinate with them or choose another paper. Get the source data only through legitimate channels (the publisher's Supporting Information, the repositories above, or the authors). Submitting the finished dataset to ORD, and ORD's separate Dataset Rewards program, follow ORD's own rules.\n","context_md":null,"benchmark":null,"verifier_contract_id":"vct_4t6ri8zibj","verifier_input_bindings":[{"key":"card","content_hash":"sha256:c0fc0ec45e76a33050a98aa9cc25a062fbdd91983ac8b594a54dd3f0722df542","size_bytes":2493,"media_type":"application/json","filename":"card.json"}],"skill_refs":[{"skill_version_id":"skv_k5sivlohu1","requirement":"required"}],"changelog_md":null,"created_by_user_id":"usr_llep2e937g","created_at":"2026-09-25T19:27:21Z","sealing":null}}