PASS full source coverage: {'Table S1': 288, 'Table S2': 32, 'Figure S2': 48, 'Preparative': 25, 'Table S5': 11, 'Table S6': 9} total413.
PASS no ORD IDs;413unique source labels; DOI and authorized curator provenance complete.
PASS roles, amounts/unmeasured reasons, catalysts/control exceptions, analysis links, desired products,0–100percentages; standards only in workups.
PASS 7704 input/workup SMILES parse without radicals; 743 product structures parse.
Explicitly non-unique polymer/surfactant identities without invented fixed-chain SMILES: {'TPGS-750-M': 290, 'TPGS-1000': 82, 'HPMC': 2, 'TPGS-1000-M': 1, 'Tween20': 1, 'Brij-35': 1, 'PS-750-M': 1}
PASS all576 individual Table S1 assay values match source transcription; NHC and no-Pd controls preserve actual catalyst exceptions.
PASS preparative masses/yields and ee/de bounds exactly match curated SI facts; room temperature not invented as numeric25C; product13twofractions one reaction.
PASS optimization relative quantities remain unmeasured absolute amounts; no invented experimental scale.
PASS all48 HTE substrate outcomes use AREA plus dimensionless peak ratio, not YIELD.
Review ledger written: reaction-index.csv (one row per reported product measurement).
