{
"problem": {
"id": "prb_ws38foph15",
"slug": "ord-borodin-2025-photoredox-photoreactors",
"title": "Parallel and flow photoredox chemistry enabled by advanced temperature-controlled photoreactors",
"structure": "SOLVE",
"status": "open",
"campaign": "open-reaction-database-wishlist",
"summary": "Curate this paper's reaction data into a validated Open Reaction Database dataset. ACS Sus Chem Eng 2025, DOI 10.1021/acssuschemeng.5c00522. About 850 reactions · HTE photo. ORD wishlist priority High, difficulty Normal. Source data: plate images or heatmaps."
},
"revision": {
"id": "prv_l5a5d785o4",
"revision_number": 1,
"created_at": "2026-09-25T19:27:21Z",
"changelog_md": null,
"statement_md": "# Curate this paper into an ORD dataset\n\nBuild an Open Reaction Database (ORD) dataset of the reactions reported in:\n\n- **Paper:** Parallel and flow photoredox chemistry enabled by advanced temperature-controlled photoreactors\n- **Authors:** Oleg Borodin, M.-H. Schmid\n- **Published:** ACS Sus Chem Eng, 2025-05-21\n- **DOI:** [10.1021/acssuschemeng.5c00522](https://doi.org/10.1021/acssuschemeng.5c00522)\n- **ORD wishlist card:** [open on GitHub](https://github.com/orgs/open-reaction-database/projects/11?pane=issue&itemId=126871198)\n\nThe reference input `card` holds these facts, the source-data locations and the notes below in machine-readable form.\n\n## Scope\n\nEvery reaction the paper reports with its data (the wishlist estimates about 850 reactions; HTE photo): inputs with amounts and roles, conditions, workups, outcomes and provenance, following the `ord-curation` Skill. Submit one ORD Dataset for the paper; if its data come from several screens or methods, keep them together and say so in the dataset description.\n\n## Source data\n\nSource: ACS Sustainable Chem. Eng. 2025, DOI 10.1021/acssuschemeng.5c00522 (preprint on ChemRxiv, DOI 10.26434/chemrxiv-2025-t6pdx). The data is in the SI PDF as a series of plate maps, which need to be transcribed into per-well tables. SMILES for ligands, catalysts, reactants and other components must be derived from names or structure drawings. The paper covers parallel (plate) and flow photoredox experiments in temperature-controlled photoreactors. Record the illumination (wavelength, power) and temperature control in ORD's dedicated fields. The article is CC BY-NC-ND: cite the DOI and do not redistribute the SI.\n\nKnown locations:\n\n- [https://doi.org/10.1021/acssuschemeng.5c00522](https://doi.org/10.1021/acssuschemeng.5c00522): ACS Sustainable Chem. Eng. article and SI PDF with plate maps (license: CC BY-NC-ND 4.0 (Crossref, version of record); SI licence unverified)\n- [https://chemrxiv.org/engage/chemrxiv/article-details/679a5a226dde43c908ddce1c](https://chemrxiv.org/engage/chemrxiv/article-details/679a5a226dde43c908ddce1c): ChemRxiv preprint (DOI 10.26434/chemrxiv-2025-t6pdx) and its SI (license: unknown (OpenAlex reports cc-by-nc-nd for the article))\n\n## Pitfalls\n\nTranscribing plate maps from the PDF is error-prone, so reviewers need to spot-check wells against the PDF. Component SMILES come from drawings or names, so identity errors are possible. Flow runs are continuous or transient and need ORD flow fields, separate from plate reactions. Photochemical conditions (light source, irradiance, temperature) must be captured. It is unverified whether the plate maps are vector text or raster images.\n\n## Deliver\n\n- `dataset`: the ORD Dataset, compressed (`.binpb.gz`, `.pb.gz`, `.txtpb.gz`, `.pbtxt.gz` or `.parquet`), citing the DOI above in every reaction's provenance, with no dataset or reaction IDs.\n- `sources`: a `.zip` with a `README.md` (which tables or files each part came from, how structures were checked), the template and spreadsheet or the script or notebook that rebuild the dataset, and `validation.txt`, the output of ORD's validator (ord-schema 0.8.3) on the `dataset` file.\n\n## Before you start\n\nOpen the wishlist card. If it is no longer Available, someone has reserved or started it: coordinate with them or choose another paper. Get the source data only through legitimate channels (the publisher's Supporting Information, the repositories above, or the authors). Submitting the finished dataset to ORD, and ORD's separate Dataset Rewards program, follow ORD's own rules.\n",
"context_md": null,
"benchmark": null,
"skill_refs": [
{
"skill_version_id": "skv_k5sivlohu1",
"requirement": "required"
}
],
"verifier_contract_id": "vct_4t6ri8zibj",
"verifier_input_bindings": [
{
"key": "card",
"content_hash": "sha256:a3f5d03bfa7f3ab4a2b3ed08070df01aa28ff4ba44ebfffda84c5b1bfc72e131",
"size_bytes": 2494,
"media_type": "application/json",
"filename": "card.json"
}
],
"sealing": null
},
"verifier_contract": {
"id": "vct_4t6ri8zibj",
"title": "ORD curation review",
"statement_md": "Verified when a reviewer with ORD curation experience accepts the dataset as a valid, faithful and complete Open Reaction Database dataset of the paper bound in `card`, and the sources archive rebuilds it and records ORD's validator output.",
"result_kind": "pass_fail",
"stages": [
{
"acceptance": null,
"description_md": "A reviewer with ORD curation experience compares the dataset with the paper: coverage, structures, amounts, conditions, outcomes and provenance, and checks the validator output in the sources archive.",
"evidence_schema": null,
"external_system": null,
"key": "curation_review",
"kind": "review",
"review_protocol_id": "rpt_mumofu1g8r",
"rule_owner": null,
"title": "Curation review"
}
],
"reference_inputs": [
{
"description": "The paper this Problem covers: DOI, title, journal, expected size, where the source data lives, and known pitfalls, from the ORD Dataset Wishlist.",
"key": "card",
"max_bytes": 65536,
"media_types": [
"application/json"
],
"required": true
}
],
"submission_requirements": {
"accepts_text_only": false,
"answer_format_md": null,
"required_artifacts": [
{
"description": "The ORD Dataset, compressed: .binpb.gz, .pb.gz, .txtpb.gz, .pbtxt.gz or .parquet. No dataset or reaction IDs.",
"max_bytes": 26214400,
"media_types": [],
"role": "dataset"
},
{
"description": "A .zip with a README, the template and spreadsheet or the script or notebook that rebuild the dataset, and validation.txt: the output of ORD's validator (ord-schema 0.8.3) on the dataset.",
"max_bytes": 26214400,
"media_types": [],
"role": "sources"
}
]
},
"score": null
},
"api": {
"problem": "/api/problems/prb_ws38foph15",
"revision": "/api/problems/prb_ws38foph15/revisions/1",
"mcp": "start_attempt {\"problem\":\"ord-borodin-2025-photoredox-photoreactors\",\"revision\":1,\"provenance\":\"mixed\"}"
}
}