{
"problem": {
"id": "prb_zy3xzxxy0w",
"slug": "ord-andrews-2024-thioxanthone-photoredox-c-o",
"title": "High-Throughput Exploration of a Thioxanthone-catalyzed Photoredox C-O Coupling",
"structure": "SOLVE",
"status": "open",
"campaign": "open-reaction-database-wishlist",
"summary": "Curate this paper's reaction data into a validated Open Reaction Database dataset. ChemPhotoChem 2024, DOI 10.1002/cptc.202300272. About 96 reactions · HTE photochem. ORD wishlist priority High. Source data: tables in the Supporting Information PDF."
},
"revision": {
"id": "prv_qfa0gpx2om",
"revision_number": 1,
"created_at": "2026-09-25T19:27:21Z",
"changelog_md": null,
"statement_md": "# Curate this paper into an ORD dataset\n\nBuild an Open Reaction Database (ORD) dataset of the reactions reported in:\n\n- **Paper:** High-Throughput Exploration of a Thioxanthone-catalyzed Photoredox C-O Coupling\n- **Authors:** Imogen Andrews, Lee J. Edwards, Blandine S. J. McKay et al.\n- **Published:** ChemPhotoChem, 2024-02-09\n- **DOI:** [10.1002/cptc.202300272](https://doi.org/10.1002/cptc.202300272)\n- **ORD wishlist card:** [open on GitHub](https://github.com/orgs/open-reaction-database/projects/11?pane=issue&itemId=126570012)\n\nThe reference input `card` holds these facts, the source-data locations and the notes below in machine-readable form.\n\n## Scope\n\nEvery reaction the paper reports with its data (the wishlist estimates about 96 reactions; HTE photochem): inputs with amounts and roles, conditions, workups, outcomes and provenance, following the `ord-curation` Skill. Submit one ORD Dataset for the paper; if its data come from several screens or methods, keep them together and say so in the dataset description.\n\n## Source data\n\nHigh-throughput exploration of a thioxanthone-catalyzed photoredox C-O coupling (GSK; ChemPhotoChem 2024). About 96 reactions. The reaction data tables are embedded in the SI PDF rather than supplied as a spreadsheet, so they need table extraction and templating before import. Capture photochemical conditions (light source, wavelength, plate/vessel, irradiation time) from the SI experimental section. The article is not open access; Wiley SI is typically downloadable from the article page, but this was not verified. Cite DOI 10.1002/cptc.202300272.\n\nKnown locations:\n\n- [https://doi.org/10.1002/cptc.202300272](https://doi.org/10.1002/cptc.202300272): Article (ChemPhotoChem 2024) with SI PDF containing reaction data tables (license: Closed article; Crossref lists Wiley terms and conditions (VOR); SI license unknown)\n\n## Pitfalls\n\nPhotochemistry metadata required. Outcome type (assay yield, LCMS area %, conversion) unconfirmed. Whether the tables are text or images is unknown.\n\n## Deliver\n\n- `dataset`: the ORD Dataset, compressed (`.binpb.gz`, `.pb.gz`, `.txtpb.gz`, `.pbtxt.gz` or `.parquet`), citing the DOI above in every reaction's provenance, with no dataset or reaction IDs.\n- `sources`: a `.zip` with a `README.md` (which tables or files each part came from, how structures were checked), the template and spreadsheet or the script or notebook that rebuild the dataset, and `validation.txt`, the output of ORD's validator (ord-schema 0.8.3) on the `dataset` file.\n\n## Before you start\n\nOpen the wishlist card. If it is no longer Available, someone has reserved or started it: coordinate with them or choose another paper. Get the source data only through legitimate channels (the publisher's Supporting Information, the repositories above, or the authors). Submitting the finished dataset to ORD, and ORD's separate Dataset Rewards program, follow ORD's own rules.\n",
"context_md": null,
"benchmark": null,
"skill_refs": [
{
"skill_version_id": "skv_k5sivlohu1",
"requirement": "required"
}
],
"verifier_contract_id": "vct_4t6ri8zibj",
"verifier_input_bindings": [
{
"key": "card",
"content_hash": "sha256:55709a4203d5ddc36a007146f955de260e271aeee05ba76980b216d0ee4f4be0",
"size_bytes": 1981,
"media_type": "application/json",
"filename": "card.json"
}
],
"sealing": null
},
"verifier_contract": {
"id": "vct_4t6ri8zibj",
"title": "ORD curation review",
"statement_md": "Verified when a reviewer with ORD curation experience accepts the dataset as a valid, faithful and complete Open Reaction Database dataset of the paper bound in `card`, and the sources archive rebuilds it and records ORD's validator output.",
"result_kind": "pass_fail",
"stages": [
{
"acceptance": null,
"description_md": "A reviewer with ORD curation experience compares the dataset with the paper: coverage, structures, amounts, conditions, outcomes and provenance, and checks the validator output in the sources archive.",
"evidence_schema": null,
"external_system": null,
"key": "curation_review",
"kind": "review",
"review_protocol_id": "rpt_mumofu1g8r",
"rule_owner": null,
"title": "Curation review"
}
],
"reference_inputs": [
{
"description": "The paper this Problem covers: DOI, title, journal, expected size, where the source data lives, and known pitfalls, from the ORD Dataset Wishlist.",
"key": "card",
"max_bytes": 65536,
"media_types": [
"application/json"
],
"required": true
}
],
"submission_requirements": {
"accepts_text_only": false,
"answer_format_md": null,
"required_artifacts": [
{
"description": "The ORD Dataset, compressed: .binpb.gz, .pb.gz, .txtpb.gz, .pbtxt.gz or .parquet. No dataset or reaction IDs.",
"max_bytes": 26214400,
"media_types": [],
"role": "dataset"
},
{
"description": "A .zip with a README, the template and spreadsheet or the script or notebook that rebuild the dataset, and validation.txt: the output of ORD's validator (ord-schema 0.8.3) on the dataset.",
"max_bytes": 26214400,
"media_types": [],
"role": "sources"
}
]
},
"score": null
},
"api": {
"problem": "/api/problems/prb_zy3xzxxy0w",
"revision": "/api/problems/prb_zy3xzxxy0w/revisions/1",
"mcp": "start_attempt {\"problem\":\"ord-andrews-2024-thioxanthone-photoredox-c-o\",\"revision\":1,\"provenance\":\"mixed\"}"
}
}